Boskovic Research Group:
Polynuclear Metal Complexes and Molecular Nanomagnets
1. C. Boskovic , M. Sadek, R. T. C. Brownlee, A. M. Bond, A. G. Wedd, "Lifting the lid on metatungstate. 1H and 183W NMR study of the six-electron reduced anion [(H)2{WIV3(OH2)3}WVIO34(OH)3]3- ", Chem. Commun. 1999, 533.
2. P. D. Prenzler, C. Boskovic , A. M. Bond, A. G. Wedd, "Coupled Electron- and Proton-tranfer Processes in the Reduction of alpha-[P2W18O62]6- and alpha-[H2W12O40]6- As Revealed by Simulation of Cyclic Voltammograms", Anal. Chem. 1999, 71, 3650.
3. C. Boskovic , K. Folting, G.Christou, "Tetranuclear manganese carboxylate clusters with imidazole-carboxylate chelating ligands. X-ray crystal structure of the 4-imidazoleacetate complex", Polyhedron 2000, 19, 2111.
4. C. Boskovic , M. Sadek, R. T. C. Brownlee, A. M. Bond, A. G. Wedd, "Electrosynthesis and solution structure of six-electron reduced forms of metatungstate, [H2W12O40]6- ", J. Chem. Soc. Dalton Trans. 2001, 187.
5. C. Boskovic , E. K. Brechin, W. E. Streib, K. Folting, D. N. Hendrickson, G. Christou, "A new class of single-molecule magnets: mixed-valent [Mn12O8Cl4(O2CPh)8(hmp)6]", Chem. Commun. 2001, 467.
6. P. Artus, C. Boskovic, J. Yoo, W. E. Streib, D. N. Hendrickson, G. Christou, "Single-Molecule Magnets: Site-Specific Ligand Abstraction from [Mn12O12(O2CR)16(H2O)4] and the Preparation and Properties of [Mn12O12(NO3)4(O2CCH2But)12(H2O)4]", Inorg. Chem. 2001, 40, 4199.
7. C. Boskovic , M. Pink, J. C. Huffman, D. N. Hendrickson, G. Christou, "Single -Molecule Magnets: Ligand-Induced Core Distortion and Multiple Jahn-Teller Isomerism in [Mn12O12(O2CMe)8(O2PPh2)8(H2O)4]", J. Am. Chem. Soc. 2001, 123, 9914.
8. C. Boskovic , E. K. Brechin, W. E. Streib, K. Folting, J. C. Bollinger, D. N. Hendrickson, G. Christou, "Single-Molecule Magnets: A new Family of Mn12 Clusters of Formula [Mn12O8X4(O2CPh)8(L)6]", J. Am. Chem. Soc. 2002, 124, 3725.
9. W. Wernsdorfer, S. Bhaduri, C. Boskovic , G. Christou, D. N. Hendrickson, "Spin-parity dependent tunnelling of magnetization in single-molecule magnets", Phys. Rev. B 2002, 65, 180403.
10. E. K. Brechin, C. Boskovic , W. Wernsdorfer, J. Yoo, A. Yamaguchi, E. C. Sañudo, T. R. Concolino, A. L. Rheingold, H. Ishimoto, D. N. Hendrickson, G. Christou, "Quantum Tunneling of Magnetization in a New [Mn18]2+ Single-Molecule Magnet with S = 13", J. Am. Chem. Soc. 2002, 124, 9710.
11. S. W. Gordon-Wylie, W. B. Blanton, B. L. Claus, C. P. Horwitz, T. J. Collins, C. Boskovic , G. Christou, "Syntheses of selected supramolecules. Toward magnetic building blocks: Synthesis of a planar Co(III)-cation radical-cobalt(III) complex of the binucleating ligand 1,2,4,5-tetrakisbenzene", Inorg. Synth. 2002, 33, 1.
12. C. Boskovic , K. Folting, J. C. Huffman, D. N. Hendrickson, G. Christou "Single-Molecule Magnets: Novel Mn8 and Mn9 Carboxylate Clusters Containing an Unusual Pentadentate Ligand Derived from Pyridine-2,6-dimethanol", Inorg. Chem. 2002, 41, 5107.
13. C. Boskovic , E. Rusanov, H. Stoeckli-Evans, H. U. Güdel, "New tri- and tetranuclear transition metal spin clusters incorporating a versatile polydentate Schiff base ligand", Inorg. Chem Commun. 2002, 5, 881.
14. C. Boskovic , J. C. Huffman, G. Christou, "A new synthetic method to Mn carboxylate clusters: reductive fragmentation of [Mn12O12(O2CR)16(H2O)4] to [Mn8O2(O2CR)14(RCO2H)4] (R = CH2But)", Chem. Commun. 2002, 2502.
15. E.C. Sañudo, E.K. Brechin, C. Boskovic , W. Wernsdorfer, J. Yoo, A. Yamaguchi, T.R. Concolino, K.A. Abboud, A.L. Rheingold, H. Ishimoto, D.N. Hendrickson, G. Christou, "[Mn18]2+ and [Mn21]4+ single-molecule magnets", Polyhedron 2003, 22, 2267.
16. R. Basler, C. Boskovic , G. Chaboussant, H. U. Güdel, M. Murrie, S. T. Ochsenbein, A. Sieber, "Molecular spin clusters: neutron scattering studies and new synthetic approaches", ChemPhysChem 2003, 4, 910. [cover]
17. C. Boskovic , G. Labat, A. Neels, H. U. Güdel, "A new core topology in pentanuclear complexes", Dalton Trans. 2003, 3671.
18. C. Boskovic , R. Bircher, P. L. W. Tregenna-Piggott, H. U. Güdel, C. Paulsen, W. Wernsdorfer, A. L. Barra, E. Khatsko, A. Neels, H. Stoeckli-Evans, "Ferromagnetic and Antiferromagnetic Intermolecular Interactions in a New Family of Mn4 Complexes with an Energy Barrier to Magnetization Reversal", J. Am. Chem. Soc. 2003, 125, 14046.
19. D. Schaniel, T. Woike, C. Boskovic , H. U. Güdel , "Evidence for two light-induced metastable electronic states in Cl3[Ru(NH3)5NO]H2O", Chem. Phys. Lett. 2004, 390, 347.
20. C. Boskovic , A Sieber, G Chaboussant, H. U. Güdel, J. Ensling, W. Wernsdorfer, A Neels, G. Labat, H. Stoeckli-Evans and S. Janssen, "Synthesis and Characterization of a New Family of Bi-, Tri-, Tetra- and Pentanuclear Ferric Complexes", Inorg. Chem. 2004, 43, 5053.
21. A. Sieber, G. Chaboussant, R. Bircher, C. Boskovic , H. U. Güdel, G. Christou, H. Mutka, "Pressure Dependence of the Magnetic Anisotropy in the Single-Molecule Magnet [Mn4O3Br(OAc)3(dbm)3]", Phys. Rev. B, 2004, 70, 172413.
22. E. K. Brechin, E. C. Sañudo, W. Wernsdorfer, C. Boskovic , J. Yoo, D. N. Hendrickson, A. Yamaguchi, H. Ishimoto, T. E. Concolino, A. L. Rheingold, G. Christou, "Single-Molecule Magnets: Structure and Properties of [Mn18O14(O2CMe)18(hep)4(hepH)2(H2O)2](ClO2)2 with Spin S = 13", Inorg. Chem. 2005 , 44 , 502.
23. D. Schaniel, T. Woike, B. Delley, C. Boskovic , K. Krämer, D. Biner, H. U. Güdel , "Long-lived light-induced metastable states in trans-[Ru(NH3)4(H2O)NO]Cl3.H2O", Phys. Chem. Chem. Phys. 2005 , 7, 1164.
24. G. Labat, C. Boskovic , H. U. Güdel, "Hexakis(mu4-2-amino-2-methylpropane-1,3-diolato)hexachloroheptairon(II,III) acetonitrile disolvate monohydrate", Acta Cryst. 2005 , E61, m611.
25. C. Boskovic , H. U. Güdel, G. Labat, A. Neels, W. Wernsdorfer, B. Moubaraki, K. S. Murray, "High nuclearity ferric complexes from a new family of polynuclear precursors", Inorg. Chem. 2005, 44, 3181.
26. A. Sieber, C. Boskovic, R. Bircher, O. Waldmann, S. T. Ochsenbein, H. U. Güdel, N. Kirchner, J. van Slageren, W. Wernsdorfer, A. Neels, H. Stoeckli-Evans, S. Janssen, F. Juranyi, H. Mutka, "Synthesis and Spectroscopic Characterization of a New Family of Ni4 Spin Clusters", Inorg. Chem. 2005, 44, 4315.
27. K. G. Alley, R. Bircher, O. Waldmann, S. T. Ochsenbein, H. U. Güdel, B. Moubaraki, K. S. Murray, F. Fernandez-Alonso, B. F. Abrahams, C. Boskovic, "Mixed-Valent Cobalt Spin Clusters: a Hexanuclear Complex and a One-Dimensional Coordination Polymer Comprised of Alternating Hepta- and Mononuclear Fragments", Inorg. Chem. 2006, 45, 8950.
28. K. G. Alley, R. Bircher, H. U. Güdel, B. Moubaraki, K. S. Murray, B. F. Abrahams, C. Boskovic, " Incorporation of a tripodal ligand with a (N, O, O)-donor set into a new family of nickel and cobalt spin clusters", Polyhedron 2007, 26, 369.
29. A. Mukherjee, C. Boskovic, R. W. Gable, "A dodecanuclear Manganese (II, III) complex of pentaerythritol", Acta Cryst. 2007, C63, m71
30. R. Bircher, B. F. Abrahams, H. U. Güdel, C. Boskovic, "Synthesis, Structure and Magnetic Properties of a Novel Tb4 Spin Cluster and Synthesis of a Tb Chain", Polyhedron 2007, 26, 3023.
31. K. G. Alley, A. Mukherjee, R. Clérac, C. Boskovic, "A new family of octanuclear Cu4Ln4(Ln = Gd, Tb and Dy) spin clusters", Dalton Trans. 2008, 59. [cover]
32. D. Schaniel, T. Woike, B. Delley, C. Boskovic, H. U. Güdel, "Photogeneration of metastable side-on N2 linkage isomers in [Ru(NH3)5N2]Cl2, [Ru(NH3)5N2]Br2, and [Os(NH3)5N2]Cl2" , Phys. Chem. Chem. Phys. 2008, 10, 5531.
33. F. Hussain, R. W. Gable, M. Speldrich, P. Kögerler, C. Boskovic, "Polyoxotungstate-encapsulated Gd6 and Yb10 complexes", Chem. Commun. 2009, DOI:10.1039/B813173B
Last updated 26.11.08
Created and maintained by Colette Boskovic