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ABOUT RESEARCH NEWS
   
   
Research in the Photophysics/Photochemistry Group
Research Interests
Research Programs
Research Facilities

Research Techniques

 

Research Interests

General Research Interests:
  • photophysics of polymers 
  • energy transport in macromolecules
  • electron transfer in multichromophoric systems
  • ultrafast dynamics in condensed phases
  • pulsed laser polymerization kinetics
  • high pressure photochemistry/photophysics 
  • time-resolved anisotropy measurements 
  • two photon and confocal fluorescence microscopy 
  • ultrafast laser spectroscopy 

Specific Research Interests:

  • electron transfer kinetics in rigidly-linked supramolecules
  • porphyrin-based photosensitisers

 

Research  Programs


See each of our group members' homepages for some specific research programs in progress.

In general, our research programs are based around the following equipment:

 

Research Facilities

Laser Systems:
  • Femtosecond titanium:sapphire oscillator system:
    • Coherent Mira 900 femtosecond titanium:sapphire pumped by an 18W Verdi DPSS laser
      • Cavity dumped with a PulseSwitch
    • APE synchronously pumped optical parametric oscillator (OPO), intracavity doubled
    • Home-built pulse picker based on a TeO2 Bragg cell and CAMAC driver
    • Frequency doubler and tripler systems
  • Femtosecond amplified titanium:sapphire system:
    • Coherent MiraSeed
    • Coherent RegA 9050 high repetition rate amplifier and a pair of OPA9450 optical parametric amplifiers
  • Picosecond dye laser system:
    • SpectraPhysics 2030 mode-locked Ar+ laser
    • TimeBandwidth Cheetah X SESAM picosecond mode-locked DPSS laser
    • Cavity dumped 3500 dye laser
    • Cavity dumped 375 dye laser
  • Nanosecond Nd:YAG/OPO systems:
    • Continuum NY-61 Q-switched Nd:YAG laser
    • Casix nanosecond optical parametric oscillator (OPO)
    • QuantaRay DCR-11 Q-switched Nd:YAG laser

Detection Systems:

  • Princeton Instruments (Roper) nanosecond ICCD camera/ARC spectrometer
  • Time-correlated single photon counting apparatus (Tennelec, Ortec, Edinburgh Instruments, Becker & Hickl SPM-830)
  • Applied Photophysics 410 arc lamp pulser unit
  • Microwave conductivity detection apparatus
  • Edinburgh Instruments Ge infrared detector

Fluorescence microscopy systems:

  • Nanonics scanning near field optical micrscope
  • Olympus FV300 scanning confocal system on IX71 frame
    • this system can use the following ultrafast laser alternatives as its light source
      • the 76 MHz output of the Ti:sapp or the OPO
      • the pulse picked output (15 MHz-single shot) of either the Ti:sapp or the OPO
      • the 250 kHz output of the RegA or OPA
      • the cavity dumped output of the picosecond dye laser.
    • associated with this system is a La Vision PicoStar HR intensified CCD camera for time resolved fluorescence imaging by either time gating or frequency modulation using the high repetition rate laser pulses

    • time resolved fluorescence measurements can also be recorded using time-correlated single photon counting methods
      • for time-resolved fluorescence decay measurements and imaging we use the following:
        • Edinburgh Instruments TCC900 TCSPC card
        • Becker & Hickl SPC830 photon counting card.
  • Olympus FV500 scanning confocal system on IX71 frame
    • this system now also includes a Jobin Yvon 550 spectrometer and N2 cooled CCD array for spectral characterisation of confocal emission
    • it also incorporates an ALV correlator for single moelcule and fluorescence correlation spectroscopy (FCS) measurements using a pair of single photon avalanche photodiodes

  • Olympus BH-2 fluorescence microscope
  • LaVision picosecond ICCD camera system

Spectrometers:

    Cary Bio50 UV-VIS spectrometer

    Cary Varian Eclipse Fluorescence Spectrometer

    Hitachi 4010 spectrofluorimeter

Cryostats:

    Oxford Instruments liquid nitrogen cryostats (Optistat DN & DN1704) 

    Leybold He cryostat 

    Oxford Microstat

Miscellaneous:

    Perkin Elmer AM-2 Autobalance

    Wyatt light scattering GPC detector

For a brief tour of the labs click this link (Quicktime 4 or higher required):

                                               Tour 1     

 

  Research Techniques
  • Time-correlated single photon counting (TCSPC)
  • Transmission pump-probe methods
  • Time-resolved evanescent wave-induced fluorescence spectroscopy (TREWIFS)
  • Fluorescence upconversion
  • Laser flash photolysis
  • Time-resolved anisotropy measurements
  • Ground-state recovery pump-probe measurements
  • Fluorescence microscopy
    • fluorescence lifetime imaging
    • two photon fluorescence microscopy

Created: May 2001; Last updated: October 14, 2005
Authorised by: Head, School of Chemistry
Designed and Maintained by: Trevor Smith